Zinc Sulphide (Zinc Sulfide) FLIR (ZnS)

Zinc Sulphide FLIR (ZnS)  SDS
Zinc Sulphide FLIR (ZnS) Data Sheet

ZnS FLIR is used for IR windows and lenses in the thermal band (8 to 14 μm) as a tough front optic in thermal imaging systems, particularly those subjected to harsh environments. ZnS FLIR grade is harder than ZnS multispectral grade.

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Transmission Range
1.0 to 13 μm
Refractive Index
2.192 at 10.6 μm
Reflection Loss
24.6% at 10.6 μm (2 surfaces)
Absorption Coefficient
0.2 cm-1 @ 10.6 μm
 
0.02 cm-1 @ 3.8 μm
Reststrahlen Peak
30.5 μm
dn/dT
+43 x 10-6/°C at 3.39 μm
dn/dμ = 0
n/a
Density
4.08 g/cc
Melting Point
1827°C - See References & Notes
Thermal Conductivity
16.7 W m-1 K-1 @ 296 K
Thermal Expansion
6.6 x 10-6/°C @ 273 K
Hardness
Knoop 160 with 50g indenter
Specific Heat Capacity
469 J Kg-1 K-1
Dielectric Constant
n/a
Youngs Modulus (E)
74.5 GPa
Shear Modulus (G)
n/a
Bulk Modulus (K)
n/a
Elastic Coefficients
n/a
Apparent Elastic Limit
103.4 MPa (15,00psi)
Poisson Ratio
0.29
Solubility
65 x 10-6 g/100g water
Molecular Weight
97.43
Class/Structure
Polycrystalline cubic, ZnS, F43m
µm No
0.42 2.516
0.46 2.458
0.50 2.419
0.54 2.391
0.58 2.371
0.62 2.355
0.66 2.342
0.70 2.332
0.74 2.323
0.78 2.316
0.82 2.310
0.86 2.305
0.90 2.301
0.94 2.297
0.98 2.294
1.00 2.292
1.40 2.275
1.80 2.267
2.20 2.263
2.60 2.260
µm No
3.00 2.257
3.40 2.255
3.80 2.253
4.20 2.251
4.60 2.248
5.00  2.246
5.40 2.244
5.80 2.241
6.20 2.238
6.60 2.235
7.00 2.232
7.40 2.228
7.80 2.225
8.20 2.221
8.60 2.217
9.00 2.212
9.40 2.208
9.80 2.203
10.2 2.198
10.6 2.192
µm No
11.0 2.186
11.4 2.18
11.8 2.173
12.2 2.167
12.6 2.159
13.0 2.152
13.4 2.143
13.8 2.135
14.2 2.126
14.6 2.116
15.0 2.106
15.4 2.095
15.8 2.084
16.2 2.072
16.6 2.059
17.0 2.045
17.4 2.03
17.8 2.015
18.2 1.998

Zinc Sulphide is produced by synthesis from Zinc vapour and H2S gas, forming as sheets on Graphite susceptors. Zinc Sulphide is microcrystalline in structure, the grain size being controlled to produce maximum strength. Forward Looking Infra-Red (FLIR) grade, which is pale yellow and translucent in the visible, is used as deposited without further treatment. It is stronger than multispectral grade. Single crystal ZnS is available, but is not common.

ZnS oxidises significantly at 300°C, exhibits plastic deformation at about 500°C and dissociates about 700°C. For safety, Zinc Sulphide windows should not be used above 250°C in normal atmosphere.

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