Sodium Fluoride NaF

Sodium Fluoride (NaF) SDS
Sodium Fluoride (NaF) Data Sheet

Sodium Fluoride has the lowest refractive index of all common optical materials which makes it of interest as a Cerenkov radiator in Particle Physics research. Crystran Ltd. has supplied Sodium Fluoride material which has been made into large arrays at CERN and it is used in Ring Imaging Cerenkov Counters (RICH).

Transmission Range
0.14 to 11 μm
Refractive Index
1.3255 at 0.6 μm
Reflection Loss
3.9% at 0.6 μm (2 surfaces)
Absorption Coefficient
1 x 10-3 cm-1 @ 7 μm (1)
Reststrahlen Peak
35.8 μm
dn/dT
-13 x 10-6 K-1 at 293K
dn/dμ = 0
1.7 μm
Density
2.79 g/cc @ 20°C
Melting Point
980°C
Thermal Conductivity
3.746 W m-1 K-1 @ 273 K
Thermal Expansion
36 x 10-6 K-1 @ 300 K
Hardness
Knoop 60 in <100>
Specific Heat Capacity
1088 J Kg-1 K-1
Dielectric Constant
6 at 1 MHz
Youngs Modulus (E)
79.01 GPa
Shear Modulus (G)
12.7 GPa
Bulk Modulus (K)
47.9 GPa
Elastic Coefficients
C11 = 79.01 C12 = 12.7 C44 = 47.9
Apparent Elastic Limit
3.2 MPa (Estimated)
Poisson Ratio
0.326
Solubility
4.22g/100g water at 18°C
Molecular Weight
42.0
Class/Structure
Cubic FCC, NaCl, Fm3m, (100) cleavage
 

 

µm No
0.14 1.55
0.145 1.499
0.161 1.438
0.175 1.410
0.186 1.393
0.199 1.3805
0.203 1.3772
0.302 1.34232
0.405 1.33194
0.486 1.32818
µm No
0.546 1.3264
0.589 1.32549
0.707 1.32372
0.811 1.32272
0.912 1.32198
1.014 1.3215
2.00 1.3170
3.1 1.313
4.1 1.308
5.1 1.301
µm No
6.1 1.292
7.1 1.282
8.1 1.269
9.1 1.252
10.3 1.233
11.3 1.209
12.5 1.18
13.8 1.142
15..1 1.093
16.7 1.029

Sodium Fluoride is produced by vacuum Stockbarger techniques. The Sodium Fluoride is very difficult to anneal and cleaves readily limiting the useful size of pieces to about 80mm. Sodium Fluoride polishes well but must be kept in dry air to maintain the quality of the surfaces and retain the deep UV transmission needed for Cerenkov radiation from this material.

REFERENCES:
(1) H.H.Li, Absorption Coefficients, Int.J.Therm, V1, No. I, 1980

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