Caesium Iodide CsI  

Caesium Iodide (CsI) SDS
Caesium Iodide (CsI) Data Sheet

Caesium Iodide (Cesium Iodide) is the material with the deepest known IR transmission, and is sometimes used for components in the widest range spectrophotometers. An extremely soft material, Cesium Iodide is extremely difficult to polish, and so performance is compromised for range. Doped with Thallium, CsI(Tl) is a useful scintillator which emits at a wavelength that is a good match for Silicon photodiodes. Arrays of Cesium Iodide are used in security imaging systems.

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Transmission Range
0.25 to 55 μm (1)
Refractive Index
1.73916 at 10 μm (1)(2)
Reflection Loss
13.6% at 10 μm
Absorption Coefficient
n/a
Reststrahlen Peak
145.8 μm
dn/dT
-99.3 x 10-6 K-1 (2)
dn/dμ = 0
6 μm
Density
4.51 g/cc
Melting Point
621 °C
Thermal Conductivity
1.1 W m-1 K-1 at 298 K (3)
Thermal Expansion
48.3 x 10-6 K-1 at 293 K (3)
Hardness
Knoop 20 with 200g indenter
Specific Heat Capacity
201 J Kg-1 K-1 (4)
Dielectric Constant
5.65 at 1 MHz
Youngs Modulus (E)
5.3 GPa
Shear Modulus (G)
6.24 GPa
Bulk Modulus (K)
12.67 GPa
Elastic Coefficients
C11=24.6 C12=6.7 C44=6.24
Apparent Elastic Limit
5.6 MPa (810psi)
Poisson Ratio
0.214
Solubility
44 g/100 g water at 0 °C
Molecular Weight
259.83
Class/Structure
Cubic CsCl, Pm3m, no cleavage, deforms.

 

µm No
0.5 1.8064
1.0 1.7572
2.0 1.7466
3.0 1.7440
4.0 1.7431
5.0 1.7424
6.0 1.7418
7.0 1.7412
8.0 1.7406
9.0 1.7399
10.0 1.7392
11.0 1.7384
12.0 1.7375
13.0 1.7365
14.0 1.7355
µm No
15.0 1.7344
16.0 1.7332
17.0 1.7319
18.0 1.7306
19.0 1.7291
20.0 1.7276
21.0 1.7260
22.0 1.7244
23.0 1.7226
24.0 1.7207
25.0 1.7188
26.0 1.7168
27.0 1.7147
28.0 1.7125
µm No
29.0 1.7101
30.0 1.7077
31.0 1.7052
32.0 1.7027
33.0 1.7000
34.0 1.6972
35.0 1.6943
36.0 1.6913
37.0 1.6882
38.0 1.6849
39.0 1.6816
40.0 1.6781
41.0 1.6746
42.0 1.6709
µm No
43.0 1.6671
44.0 1.6631
45.0 1.6591
46.0 1.6549
47.0 1.6505
48.0 1.6460
49.0 1.6414
50.0 1.6366

Caesium Iodide is grown by sealed ampoule Stockbarger techniques with ingots of approximately 70mm diameter. CsI is very soft and pliable.

IUPAC International Union of Pure and applied Chemistry recommends the spelling as Cesium. UK Useage is Caesium.

REFERENCES:
(1) Handbook Optical Constants, ed Palik, V2, ISBN 0-12-544422-2
(2) Rodney, J.Opt.Soc.Am. V45, p987, 1955
(3) Combes et al, J.Opt.Soc.Am. V41, p215, 1951
(4) Kelly, Bureau of Mines Bulletin, No371, p51, 1934

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