Lithium Fluoride LiF

Lithium Fluoride (LiF) SDS
Lithium Fluoride (LiF) Data Sheet

Lithium fluoride is the material with the most extreme UV transmission of all and is used for special UV optics. Lithium fluoride transmits well into the VUV region at the hydrogen Lyman-alpha line (121nm) and beyond. Lithium fluoride is also used for X-ray monochromator plates where its lattice spacing makes it the most useful analysis crystal.

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Transmission Range
0.12 to 6 μm
Refractive Index
1.392 at 0.6 μm (1)
Reflection Loss
5.2% at 0.6 μm (2 surfaces)
Absorption Coefficient
5.9 x 10-3 cm-1 at 4.3 μm @ 300K (5)
Reststrahlen Peak
25 μm
dn/dT
-16 x 10-6 K-1 at 1.15 μm
dn/dμ = 0
1.3 μm
Density
2.639 g/cc
Melting Point
848°C (6)
Thermal Conductivity
11.3 W m-1 K-1 at 314 K (2)
Thermal Expansion
37 x 10-6 K-1 at 283 K (2)
Hardness
Knoop 102 with 600g indenter (2)
Specific Heat Capacity
1562 J Kg-1 K-1
Dielectric Constant
0.1
Youngs Modulus (E)
64.97 GPa (2)
Shear Modulus (G)
54.14 GPa (2)
Bulk Modulus (K)
62.03 GPa (2)
Elastic Coefficients
C11 = 112 C12 = 46 C44 = 63.5 (3)
Apparent Elastic Limit
11.2 MPa (1620psi) (4)
Poisson Ratio
0.326 (calculated)
Solubility
0.27g/100g water at 20°C
Molecular Weight
25.94
Class/Structure
Cubic FCC, Fm3m (#221), NaCl structure, (100) cleavage
 

 

µm No
0.106 1.9130
0.108 1.8330
0.110 1.7770
0.121 1.6240
0.130 1.5690
0.140 1.5300
0.150 1.5030
0.160 1.4840
0.170 1.4690
0.180 1.4850
0.190 1.4455
0.200 1.4391
0.220 1.4291
0.250 1.4189
0.260 1.4164
0.270 1.4141
0.280 1.4121
µm No
0.290 1.4103
0.300 1.4087
0.310 1.4073
0.320 1.4060
0.330 1.4048
0.340 1.4037
0.350 1.4028
0.360 1.4019
0.400 1.3989
0.500 1.3943
0.600 1.3918
0.700 1.3902
0.800 1.3890
0.900 1.3880
1.000 1.3871
1.500 1.3832
2.000 1.3788
µm No
2.500 1.3788
3.000 1.3666
3.500 1.3587
4.000 1.3494
4.500 1.3388
5.000 1.3266
5.100 1.3240
5.200 1.3213
5.300 1.3186
5.400 1.3158
5.500 1.3129
5.600 1.3099
5.700 1.3069
5.800 1.3038
5.900 1.3007
6.000 1.2975

Lithium Fluoride is grown by vacuum Stockbarger technique in ingots approximately 100mm diameter. Lithium Fluoride cleaves easily and must be worked with extreme care. Polishing, particularly steep radii, often causes surface "rip-out".

REFERENCES:
(1) Laporte et. al. J.Opt. Soc. Am. V73, No 8, p1062
(2) Combes et. al. J.Opt. Soc. Am. V41, p215. 1951
(3) Huntingdon, Phys Review. V72, p321, 1947
(4) Ballard et. al. J.Opt. Soc. Am. V42, p684. 1952
(5) H.H.Li, Absorption Coefficients, Int.J.Therm, V1, No. I, 1980
(6) T.B.Douglas & J.L.Dever, J. Am. Chem.Soc, 1954,76 (19), p4826

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